Cleopatra 2525 (2000)

Cleopatra 2525 is a 2000-2001 American/New Zealand science fiction series that aired in first-run syndication alongside Jack of All Trades and Xena: Warrior Princess. It starred Jennifer Sky as Cleo, a woman who is cryogenically frozen in 2001 and awakens in 2525 to find that the world has been taken over by "the Baileys," deadly robots who control the surface world. Cleo joins an underground resistance group led by Hel (Gina Torres), seeking to defeat the Baileys. The series costarred Victoria Pratt and Patrick Kake.

Mind Games (Season 1, Episode 4)
Raina (Danielle Cormack), a powerful telepath, escapes from prison. She uses her mind control powers on the team, with only Cleo being immune.

In Your Boots (Season 2, Episode 10)
Criminal Kreegan (Joel Tobeck) is sentenced to death. However, he has a plan to escape execution, one which involves switching bodies with Hel. Can Sarge and Cleo figure out what's going on before Hel is accidentally put to death?

No Thanks for the Memories (Season 2, Episode 12)
Cleo hypnotizes Sarge to access her memories.