Mazinger Z

Mazinger Z (Japanese: マジンガーZ Hepburn: Majingā Zetto, known briefly as Tranzor Z in the United States) is a Japanese super robot manga series written and illustrated by Go Nagai. An anime adaptation was aired on Fuji TV from 1972 to 1974. Mazinger Z has spawned several sequels and spinoff series, among them UFO Robot Grendizer and Mazinkaiser.

The First Encounter!! Demon Officer Viscount Pygman!! (Episode 83)
Kouji's friends are mind controlled by Pygman's hypno ray.

Deadly Explosion!! The Terrible Viscount Pygman!! (Episode 87)
Saya and Shiro are hypnotized to fall asleep by Pygman's hypno ray.